This is Pentecost by Duccio. It is a panel from his magnificent 14th century many-paneled Maesta altarpiece. The artistic medium is egg tempera on poplar wood with extensive use of gold gilding. The dimensions are about 14.8 by 16.7 inches.
At the above link for the Maesta altarpiece, one can read about how this masterwork was dismantled in the 18th century as part of a remodeling project. The altarpiece was split up with some panels lost and others now in various locations around the world. This one is permanently housed in the Cathedral Museum in Siena, Italy and is on display there.
I find it interesting that Duccio depicted a tongue of fire coming down on Our Lady's head, just as they come down on the heads of each of the Apostles. The explanation for this is that scripture expressly states that Mary was present at the Pentecost events and also states that the fire came down on all who were present so Our Lady must have been included: Acts 1:14 and 2:1-4.
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